We’re being asked to determine the molar mass of an unknown solute present in 50.0 g benzene to get a change in freezing point of 0.41˚C.
Recall that the freezing point of a solution is lower than that of the pure solvent and the change in freezing point (ΔTf) is given by:
The change in freezing point is also related to the molality of the solution:
i = van’t Hoff factor
m = molality of the solution (in m or mol/kg)
Kf = freezing point depression constant (in ˚C/m)
Recall that the molality of a solution is given by:
For this problem, we need to do the following:
Step 1: Determine the molality of the solution.
Step 2: Calculate the moles of the unknown solute.
Step 3: Calculate the molar mass of the unknown solute.
When 0.81 g of an unknown non-electrolyte is dissolved in 50.0 g of benzene, the freezing point decreased by 0.41 degrees C.If the Kfp of the solvent is 5.12 K/m, calculate the molar mass of the unknown solute.
a. 20.23 g/mol
b. 202.3 g/mol
c. 2023 g/mol
d. not enough information is given