Ch.13 - Chemical KineticsWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

Solution: The reaction of CO with Cl2 gives phosgene (COCl2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:

Cl2 (g) ⇌ 2 Cl (g) (fast, krepresents the forward rate constant, k−1 the reverse rate constant)
CO(g) + Cl(g) ⟶ COCl(g) (slow, k2 the rate constant)
COCl(g) + Cl(g) ⟶ COCl2 (g) (fast, k3 the rate constant)

(a) Write the overall reaction.

Solution: The reaction of CO with Cl2 gives phosgene (COCl2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:Cl2 (g) ⇌ 2 Cl (g) (fast, k1 represents t

Problem

The reaction of CO with Cl2 gives phosgene (COCl2), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises:

Cl2 (g) ⇌ 2 Cl (g) (fast, krepresents the forward rate constant, k−1 the reverse rate constant)
CO(g) + Cl(g) ⟶ COCl(g) (slow, k2 the rate constant)
COCl(g) + Cl(g) ⟶ COCl2 (g) (fast, k3 the rate constant)

(a) Write the overall reaction.