Ch.13 - Chemical KineticsWorksheetSee all chapters
All Chapters
Ch.1 - Intro to General Chemistry
Ch.2 - Atoms & Elements
Ch.3 - Chemical Reactions
BONUS: Lab Techniques and Procedures
BONUS: Mathematical Operations and Functions
Ch.4 - Chemical Quantities & Aqueous Reactions
Ch.5 - Gases
Ch.6 - Thermochemistry
Ch.7 - Quantum Mechanics
Ch.8 - Periodic Properties of the Elements
Ch.9 - Bonding & Molecular Structure
Ch.10 - Molecular Shapes & Valence Bond Theory
Ch.11 - Liquids, Solids & Intermolecular Forces
Ch.12 - Solutions
Ch.13 - Chemical Kinetics
Ch.14 - Chemical Equilibrium
Ch.15 - Acid and Base Equilibrium
Ch.16 - Aqueous Equilibrium
Ch. 17 - Chemical Thermodynamics
Ch.18 - Electrochemistry
Ch.19 - Nuclear Chemistry
Ch.20 - Organic Chemistry
Ch.22 - Chemistry of the Nonmetals
Ch.23 - Transition Metals and Coordination Compounds

Solution: Given the following reactions and the corresponding rate laws, in which of the reactions might the elementary reaction and the overall reaction be the same?
(a) Cl2 + CO ⟶ Cl2CO, rate = k[Cl2]3/2 [CO]
(b) PCl3 + Cl2 ⟶ PCl5, rate = k[PCl3][Cl2]
(c) 2 NO + H2 ⟶ N2 + H2O, rate = k[NO][H2]
(d) 2 NO + O2 ⟶ 2 NO2, rate = k[NO]2 [O2]
(e) NO + O3 ⟶ NO2 + O2, rate = k[NO][O3]

Solution: Given the following reactions and the corresponding rate laws, in which of the reactions might the elementary reaction and the overall reaction be the same?(a) Cl2 + CO ⟶ Cl2CO, rate = k[Cl2]3/2 [CO](

Problem

Given the following reactions and the corresponding rate laws, in which of the reactions might the elementary reaction and the overall reaction be the same?
(a) Cl2 + CO ⟶ Cl2CO, rate = k[Cl2]3/2 [CO]
(b) PCl3 + Cl2 ⟶ PCl5, rate = k[PCl3][Cl2]
(c) 2 NO + H2 ⟶ N2 + H2O, rate = k[NO][H2]
(d) 2 NO + O2 ⟶ 2 NO2, rate = k[NO]2 [O2]
(e) NO + O3 ⟶ NO2 + O2, rate = k[NO][O3]